Diesel is an increasingly popular fuel in European cars, with over half of new registrations of this type. What are the differences between these two propellants?
Conventional diesel and petrol are both produced from mineral oil, but the precise refining methods vary. Diesel is in principle easier to refine than gasoline, however it contains more pollutants that must be extracted before it can reach the same levels of emissions as petrol. Per litre, diesel contains more energy than petrol and the vehicle’s engine combustion process is more efficient, adding up to higher fuel efficiency and lower CO2 emissions when using diesel.
Diesel and petrol engines
By virtue of the combustion process and the overall engine concept, a diesel engine can be up to 40% more efficient than a spark-ignited petrol engine with the same power output, ceteris paribus, particularly with new ‘low’ compression diesels.
The calorific value of diesel fuel is roughly 45.5 MJ/kg (megajoules per kilogram), slightly lower than petrol which is 45.8 MJ/kg. However, diesel fuel is denser than petrol and contains about 15% more energy by volume (roughly 36.9 MJ/litre compared to 33.7 MJ/litre). Accounting for the difference in energy density, the overall efficiency of the diesel engine is still some 20% greater than the petrol engine, despite the diesel engine also being heavier.
1kg of diesel burnt under ideal conditions will produce 2.65kg of CO2. 1kg of petrol burnt under ideal conditions will produce 2.3kg of CO2.
Petrol versus diesel: refinery processing
Crude oil contains hundreds of different types of hydrocarbons all mixed together and, depending on the source of the crude oil, different impurities. In order to produce petrol, diesel or any other oil-based products, the hydrocarbons have to be separated, by refining of one type or another:
Different hydrocarbon chain lengths all have progressively higher boiling points the longer the chain, so they can all be separated by a process known as fractional distillation. During the process, crude oil is heated in a distillation column, and the different hydrocarbon chains are extracted as a vapour according to their vaporisation temperatures and then recondensed.
- Petrol is made of a mix of alkanes and cycloalkanes with a chain length of between 5-12 carbon atoms. These boil between 40°C and 205°C
- Gas oil or Diesel is made alkanes containing 12 or more carbon atoms. These have a boiling point between 250°C and 350°C
After distillation, there are various techniques that are used to convert some fractions to others:
- cracking, which breaking large hydrocarbon chains into smaller ones
- unification – which combines smaller hydrocarbon chains to make larger ones
- alteration – which re-arranges various isomers to make desired hydrocarbons
For example, this allows a refinery to turn diesel fuel into petrol fuel, depending on the demand for petrol. Refineries will also combine various fractions (processed, unprocessed) into mixtures to make desired products. For example, different mixtures of hydrocarbon chains can create petrols with different octane ratings.
Distillated and chemically processed fractions are treated to remove impurities, such as organic compounds containing sulphur, nitrogen, oxygen, water, dissolved metals and inorganic salts.